Ecological Assessment of Storm Impacts

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Data Collection

Malathion

CAS Number: 121-75-5

Basic Information

The chemical structure of Malathion Synonym(s): Dimethyl phosphorodithioate of diethyl mercaptosuccinate; Calmathion; Carbethoxy malathion; Carbetovur; Carbetox; Carbofos; Carbophos; Celthion; Chemathion; Cimexan; Cleensheen; Compound 4049
Formula: C10H19O6PS2
Molecular Weight: 330.35
Boiling Point (°C): 156
Melting Point (°C): 2.85
Contaminant Type: Malathion is an insecticide.
Notes: Colorless to brown liquid with a mild, skunk-like odor. Deep brown to yellow liquid

Solubility (in water)

  • Solubility: 145 mg/l g
  • Solubility: 145 mg/l e
    Temperature (°C): 20

Half-Life (in soil unless otherwise noted)

  • t1/2: 3-7 days f
    Environment: Scientific judgement based upon unacclimated aerobic soil grab sample data.
  • t1/2: 1-25 days a
  • t1/2: 0.05 days e
    Temperature (°C): 18-22
    Notes: Aerobic biodegration half-life at an initial concentration of 2 ppm, using a mixture of nonacclimated sludge, field soil, and river sediment as inoculum, in a stirred flask, the major bacterial types in the activated sludge have been characterized as follows: Flavobacterium 35%; Alcaligenes 30%; Corynebacterium 20%; Pseudomonas 15%

Toxicity Effects

  • Organism Type: Algae e
    Scientific Name: Tetrahymena pyriformis
    Toxicity: 10 mg/l
    Test: 96h EC9
  • Organism Type: Crustaceans e
    Common Name: Sand shrimp, sevenspine bay shrimp
    Scientific Name: Crangon septemspinosa
    Toxicity: 33 µg/l
    Test: 96h LC50,S
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 3 µg/l
    Test: 1w LC50
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.6 µg/l
    Test: 21d NOEC
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.9 µg/l
    Test: 24h LC50
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 1.8 µg/l
    Test: 48h LC50
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Toxicity: 1.8 µg/l
    Test: 48h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus fasciatus
    Toxicity: 0.5 µg/l
    Test: 5d LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus fasciatus
    Toxicity: 0.76 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus lacustris
    Toxicity: 1 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus pseudolimnaeus
    Toxicity: 0.023 µg/l
    Test: 30d LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus pseudolimnaeus
    Toxicity: 0.008 µg/l
    Test: 30d NOEC
  • Organism Type: Crustaceans e
    Scientific Name: Orconectes nais
    Toxicity: 180 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Common Name: Long-armed hermit crab
    Scientific Name: Pagurus longicarpus
    Toxicity: 83 µg/l
    Test: 96h LC50,S
  • Organism Type: Crustaceans e
    Common Name: Migrant prawn, oriental shrimp
    Scientific Name: Palaemon macrodactylus
    Toxicity: 34 µg/l
    Test: 96h LC50,F
  • Organism Type: Crustaceans e
    Common Name: Migrant prawn, oriental shrimp
    Scientific Name: Palaemon macrodactylus
    Toxicity: 22 µg/l
    Test: 96h LC50,S
  • Organism Type: Crustaceans e
    Common Name: Mississippi grass shrimp
    Scientific Name: Palaemonetes kadiakensis
    Toxicity: 9 µg/l
    Test: 5d LC50
  • Organism Type: Crustaceans e
    Common Name: Mississippi grass shrimp
    Scientific Name: Palaemonetes kadiakensis
    Toxicity: 12 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans af
    Common Name: Daggerblade grass shrimp
    Scientific Name: Palaemonetes pugio
    Life Stage: Adult
    Toxicity: 38.19 µg/l
    Test: 96h LC50,S
    Notes: Shriimp were exposed to malathion for 96h at 20% salinity
  • Organism Type: Crustaceans af
    Common Name: Daggerblade grass shrimp
    Scientific Name: Palaemonetes pugio
    Life Stage: Larval
    Toxicity: 13.24 µg/l
    Test: 96h LC50,S
    Notes: 18 day old larvae. Shriimp were exposed to malathion for 96h at 20% salinity
  • Organism Type: Crustaceans af
    Common Name: Daggerblade grass shrimp
    Scientific Name: Palaemonetes pugio
    Life Stage: Larval
    Toxicity: 9.06 µg/l
    Test: 96h LC50,S
    Notes: Newly hatch larvae. Shriimp were exposed to malathion for 96h at 20% salinity
  • Organism Type: Crustaceans e
    Common Name: Common grass shrimp
    Scientific Name: Palaemonetes vulgaris
    Toxicity: 82 µg/l
    Test: 96h LC50,S
  • Organism Type: Crustaceans e
    Common Name: Red-swamp crayfish
    Scientific Name: Procambarus clarkii
    Toxicity: 49 mg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Simocephalus serrulatus
    Toxicity: 3.5 µg/l
    Test: 48h LC50
  • Organism Type: Fish e
    Common Name: Perch
    Toxicity: 0.26 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Sunfish
    Toxicity: 0.17 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: American eel
    Scientific Name: Anguilla rostrata
    Toxicity: 0.5 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: American eel
    Scientific Name: Anguilla rostrata
    Toxicity: 82 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Goldfish
    Scientific Name: Carassius auratus
    Toxicity: 11 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Scientific Name: Cirrhinus mrigala
    Toxicity: 5.4 mg/l
    Test: 48h LC50
  • Organism Type: Fish e
    Common Name: Bullhead
    Scientific Name: Cottus gobio
    Toxicity: 13 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Sheepshead minnow
    Scientific Name: Cyprinodon variegatus
    Toxicity: 51 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Sheepshead minnow
    Scientific Name: Cyprinodon variegatus
    Toxicity: 6 µg/l
    Test: MATC Life Cycle
  • Organism Type: Fish e
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 9 mg/l
    Test: 48h LC50
  • Organism Type: Fish e
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 9.8 - 10 mg/l
    Test: 48h LC50
  • Organism Type: Fish e
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 6.6 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 1.9 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Bass
    Scientific Name: Dicentrarchus labrax
    Toxicity: 0.29 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Banded killifish
    Scientific Name: Fundulus diaphanus
    Toxicity: 0.24 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Mummichog
    Scientific Name: Fundulus heteroclitus
    Toxicity: 70; 80 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Striped killifish
    Scientific Name: Fundulus majalis
    Toxicity: 250 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Mosquitofish
    Scientific Name: Gambusia affinis
    Toxicity: 0.2 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Alaskan stickleback, three-spine stickleback
    Scientific Name: Gasterosteus aculeatus
    Toxicity: 77 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Black bullhead
    Scientific Name: Ictalurus melas
    Toxicity: 12,900 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Channel catfish
    Scientific Name: Ictalurus punctatus
    Toxicity: 8,970 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Flagfish
    Scientific Name: Jordanella floridae
    Toxicity: 8.6 - 11 µg/l
    Test: 110d MATC,F
  • Organism Type: Fish e
    Common Name: Flagfish
    Scientific Name: Jordanella floridae
    Toxicity: 349 µg/l
    Test: 96h LC50,F
  • Organism Type: Fish e
    Common Name: Green sunfish
    Scientific Name: Lepomis cyanellus
    Toxicity: 120 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Pumpkinseed
    Scientific Name: Lepomis gibbosus
    Toxicity: 0.48 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 120 µg/l
    Test: 24h LC50
  • Organism Type: Fish e
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 110 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 0.1 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Redear sunfish
    Scientific Name: Lepomis microlophus
    Toxicity: 170 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Atlantic silverside
    Scientific Name: Menidia menidia
    Toxicity: 125 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Largemouth bass
    Scientific Name: Micropterus salmoides
    Toxicity: 285 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: White perch
    Scientific Name: Morone americana
    Toxicity: 1.1 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Striped bass
    Scientific Name: Morone saxatilis
    Toxicity: 0.039 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Striped mullet
    Scientific Name: Mugil cephalus
    Toxicity: 550 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Coho salmon or silver salmon
    Scientific Name: Oncorhynchus kisutch
    Toxicity: 0.1 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Coho salmon or silver salmon
    Scientific Name: Oncorhynchus kisutch
    Toxicity: 101 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 100 µg/l
    Test: 24h LC50
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 0.17 mg/l
    Test: 96h LC50
  • Organism Type: Fish g
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 200 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Yellow perch
    Scientific Name: Perca flavescens
    Toxicity: 263 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Minnow
    Scientific Name: Phoxinus phoxinus
    Toxicity: 8.7 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 9,000 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 14 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Guppy
    Scientific Name: Poecilia reticulata
    Toxicity: 0.819 µg/l
    Test: 1w LC50
  • Organism Type: Fish e
    Common Name: Guppy
    Scientific Name: Poecilia reticulata
    Toxicity: 1.2 mg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Columbia River redband trout
    Scientific Name: Salmo gairdneri
    Toxicity: 170 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Brown trout
    Scientific Name: Salmo trutta
    Toxicity: 200 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Brown trout
    Scientific Name: Salmo trutta
    Toxicity: 0.2 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Catfish
    Scientific Name: Siluriformes (Order)
    Toxicity: 9 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Northern puffer
    Scientific Name: Sphaeroides maculatus
    Toxicity: 3250 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Bluehead
    Scientific Name: Thalassoma bifasciatum
    Toxicity: 27 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Eastern mudminnow
    Scientific Name: Umbra pygmaea
    Toxicity: 0.14 µg/l
    Test: 14d LC50,F
  • Organism Type: Fish e
    Common Name: Eastern mudminnow
    Scientific Name: Umbra pygmaea
    Toxicity: 0.24 µg/l
    Test: 96h LC50,S
  • Organism Type: Mammals g
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Toxicity: 5500 mg/kg
    Test: LD50
    Formulation: > or = 95% Tech
  • Organism Type: Molluscs e
    Common Name: Eastern oyster
    Scientific Name: Crassostrea virginica
    Life Stage: Larval
    Toxicity: 2660 µg/l
    Test: 14d LC50,S
  • Organism Type: Molluscs e
    Common Name: Eastern oyster
    Scientific Name: Crassostrea virginica
    Life Stage: Egg
    Toxicity: 9070 µg/l
    Test: 48h LC50,S

Octanol-Water Partition Coefficients

  • Log Kow: 2.89 e
    Formulation: at 20C

Resource Map: Click below to open in a new window to view or print.
Potential applications of this contaminant in the St. Johns Water River Management District

Work Cited

a Beyond pesticides fact sheets. Pages retrieved November, 2003 from http://www.beyondpesticides.org. Beyond Pesticides, Washington, DC.
e Verschueren, K. 1996. Handbook of Environmental Data on Organic Chemicals, 3rd edition. John Wiley & Sons, Inc., New York.
f Howard, P. H., R. S. Boethling, W. F. Jarvis, W. M. Meylan, and E. M. Michalenko. 1991. Handbook of Environmental Degradation Rates. Lewis Publishers., Chelsea, MI.
g Meister, R. T., and C. Sine (Ed). 2003. Crop Protection Handbook, volume 89. Meister Publishing Company, Willoughby, OH.
af Key, P., M. H. Fulton, G. I. Scott, S. L. Layman, and E. F. Wirth. 1998. Lethal and sublethal effects of malathion on three life stages of the grass shrimp, Palaemonetes pugio. Aquatic Toxicology 40:311-322.