Ecological Assessment of Storm Impacts

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anthracene

CAS Number: 120-12-7

Basic Information

The chemical structure of anthracene Synonym(s): Paranaphthalene; Anthracene; Anthracene ; anthracin; Anthraxcene; green oil; tetra olive n2g;
Formula: C14H10
Molecular Weight: 178.233
Boiling Point (°C): 342
Melting Point (°C): 218
Contaminant Type: anthracene is a polyclyclic aromatic hydrocarbon.
Notes: MONOCLINIC PLATES FROM ALCOHOL RECRYSTALLIZATION; WHEN PURE, COLORLESS WITH VIOLET FLUORESCENCE ; When crystallized from benzene, colorless, lustrous plates are formed which exhibit a blue fluorescence ; YELLOW CRYSTALS WITH BLUE FLUORESCENCE

Solubility (in water)

  • Solubility: 4.34E-06 g/100ml d
  • Solubility: 4.10E-02 mg/kg ao
    Temperature (°C): 25
  • Solubility: 7.50E-02 mg/kg ao
    Temperature (°C): 25
  • Solubility: 4.46E-02 mg/kg ao
    Temperature (°C): 25
  • Solubility: 7.50E-02 mg/kg ao
    Temperature (°C): 29
  • Solubility: 7.30E-02 mg/kg ao
    Temperature (°C): 25
  • Solubility: 1.29E+00 mg/l ak
    Temperature (°C): 25
    Formulation: in distilled water
  • Solubility: 6.00E-01 mg/l ak
    Temperature (°C): 25
    Formulation: in salt water
  • Solubility: 7.50E-02 mg/l ak
    Temperature (°C): 15
  • Solubility: 7.30E-02 mg/l an
    Temperature (°C): 25

Half-Life (in soil unless otherwise noted)

  • t1/2: 3.3; 108; 129; 138; 143; 175 days ak
    Environment: at initial conc between 3 and 40 mg/kg soil
  • t1/2: 108-175 days ak
    Environment: in soil
  • t1/2: 57-210 days ak
    Environment: in unacclimatised sediments
  • t1/2: 5-7 days ak
    Environment: in oil-treated sediments
  • t1/2: 3.3; 108-139 days al
    Environment: biodegradation in soils
  • t1/2: 1600 days an
    Environment: by oxidation
  • t1/2: 18-300 day an
    Environment: by volatilization (may be competitive with adsorption)
  • t1/2: >11.3 day an
    Environment: biotransformation/biodegradation
  • t1/2: ~35 minutes an
    Environment: by photolysis
  • t1/2: 12 months ak
    Temperature (°C): 20
    Environment: abiotic degradation in sandy loam in the dark at 700 mg/kg
  • t1/2: 6 months ak
    Temperature (°C): 20
    Environment: biodegradation in sandy loam in the dark at 700 mg/kg
  • t1/2: 0.14-1.26 years f
    Environment: Based upon aerobic soil die-away test data

Toxicity Effects

  • Organism Type: Crustaceans ak
    Scientific Name: Artemia salina
    Toxicity: 0.02 mg/l
    Test: 3h LC50
  • Organism Type: Crustaceans ak
    Scientific Name: Artemia spp
    Toxicity: > 0.05 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.02 mg/l
    Test: 2h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.035; 3.03 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Toxicity: 0.001; > 0.03 mg/l
    Test: 24h EC50
  • Organism Type: Fish ak
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 11.9 µg/l
    Test: 96h LC50
  • Organism Type: Fish ak
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 5 mg/l
    Test: 24h NOEC
  • Organism Type: Fish ak
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 0.36 mg/l
    Test: 24h LC50

Soil Organic Carbon/Water Partition Coefficients

  • Koc: Log Koc: 4.15 ay
  • Koc: 26000 ak

Octanol-Water Partition Coefficients

  • Log Kow: Kow: 28200 ao
  • Log Kow: 4.5 ay
  • Log Kow: 4.45 ak
  • Log Kow: 4.45 an

Work Cited

d ChemFinder. Cambridge MA: CambridgeSoft Corporation. Retrieved November, 2003 from http://chemfinder.cambridgesoft.com
f Howard, P. H., R. S. Boethling, W. F. Jarvis, W. M. Meylan, and E. M. Michalenko. 1991. Handbook of Environmental Degradation Rates. Lewis Publishers., Chelsea, MI.
ak Verschueren, K. 2001. Handbook of Environmental Data on Organic Chemicals, 4th edition. John Wiley & Sons, Inc., New York.
al Speclab.com. 2003. Spectrum chemcial fact sheet. Pages retrieved April 2005 from http://www.speclab.com/compound/. Spectrum Laboratory Inc, Ft. Lauderdale, FL and Savannah, GA.
an USEPA. 1979. Water-related environmental fate of 129 priority pollutants. Vol. II. Halogenated liphatic hydrocarbons, halogenated ethers, monocyclic aromatics, phthalate esters, polycyclic aromatic hydrocarbons, nitrosamines, and miscellaneous compounds. Environmental Protection Agency, Office of Water Planning and Standards, EPA-440/4-79-029b. NTIS no. PB 80-204381, Washington, DC.
ao Santodonato, J., P. Howard, D. Basu, S.D. Lee, Si Duk, and L. Grant. 1981. Health and ecological assessment of polynuclear aromatic hydrocarbons. Pages 1-364 in Journal of environmental pathology and toxicology, volume 5(1). Park Forest South, Ill. : Pathotox Publishers.
ay Nagpal, N. K. 1993. Ambient Water Quality Criteria For Polycyclic Aromatic Hydrocarbons (PAHs). Pages retrieved April 2005 from http://www.env.gov.bc.ca/wat/wq/BCguidelines/pahs/index.html. British Columbia Ministry of Environment.