Ecological Assessment of Storm Impacts

Overview > Data Collection

Data Collection

Phenanthrene

CAS Number: 85-01-8

Basic Information

The chemical structure of Phenanthrene Synonym(s): phenanthracene
Formula: C14H10
Molecular Weight: 178.233
Boiling Point (°C): 340
Melting Point (°C): 99.5
Contaminant Type: Phenanthrene is a polyclyclic aromatic hydrocarbon.
Notes: MONOCLINIC PLATES FROM ALCOHOL; COLORLESS SHINING CRYSTALS; LEAFLETS

Solubility (in water)

  • Solubility: 1.15E+00 mg/kg ao
    Temperature (°C): 25
  • Solubility: 1.00E+00 mg/kg ao
    Temperature (°C): 25
  • Solubility: 1.60E+00 mg/kg ao
    Temperature (°C): 29
  • Solubility: 1.18E-04 g/100ml d
  • Solubility: 4.20E-01 mg/l ak
    Temperature (°C): 8.5
  • Solubility: 8.20E-01 mg/l ak
    Temperature (°C): 21
  • Solubility: 1.30E+00 mg/l ak
    Temperature (°C): 30
  • Solubility: 1.29E+00 mg/l an
    Temperature (°C): 25

Half-Life (in soil unless otherwise noted)

  • t1/2: 16-200 days f
    Environment: Based upon aerobic soil die-away test data
  • t1/2: 26 days ak
    Environment: in a soil system at initial conc of 2 mg/kg
  • t1/2: 8000000 days an
    Environment: by oxidation
  • t1/2: 24 months ak
    Temperature (°C): 20
    Environment: abiotic degradation in sandy loam in the dark at 700 mg/kg
  • t1/2: 3 months ak
    Temperature (°C): 20
    Environment: biodegradation in sandy loam in the dark at 700 mg/kg

Toxicity Effects

  • Organism Type: Crustaceans ak
    Scientific Name: Artemia salina
    Toxicity: 0.2; 0.3; 0.5 mg/l
    Test: 24h EC50
  • Organism Type: Crustaceans ak
    Scientific Name: Artemia salina
    Toxicity: > 6.7 mg/l
    Test: 3h LC50
  • Organism Type: Crustaceans ak
    Scientific Name: Artemia spp
    Toxicity: 0.7 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.45 mg/l
    Test: 2h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.2; 0.7; 1.2 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Toxicity: 734 µg/l
    Test: 2d IC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Toxicity: > 1.1 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Toxicity: 0.1 mg/l
    Test: 96h LC50
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Life Stage: Neonates
    Toxicity: < 0.11 mg/l
    Test: NOEC, growth
    Formulation: neonates lifetime
  • Organism Type: Crustaceans ak
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Life Stage: Neonates
    Toxicity: 0.11 mg/l
    Test: NOEC, reproduction
    Formulation: neonates lifetime
  • Organism Type: Crustaceans ak
    Scientific Name: Neanthes arenaceodentata
    Toxicity: 0.6 mg/l
    Test: 96h LC50
    Temperature (°C): 22
    Formulation: in seawater
  • Organism Type: Crustaceans ak
    Common Name: Estuarine Mud Crab
    Scientific Name: Rhithropanopeus harrisii
    Life Stage: Zoea
    Toxicity: 0.15 mg/l
    Test: 1w NOLC
    Notes: Megalops (at age 1)
  • Organism Type: Fish ak
    Common Name: Largemouth bass
    Scientific Name: Micropterus salmoides
    Life Stage: Eggs through 4 days after hatching
    Toxicity: 0.18 mg/l
    Test: 1w LC50
  • Organism Type: Fish ak
    Common Name: Columbia River redband trout
    Scientific Name: Salmo gairdneri
    Life Stage: Eggs through 4 days after hatching
    Toxicity: 0.04 mg/l
    Test: 4w LC50
  • Organism Type: Fish ak
    Common Name: Columbia River redband trout
    Scientific Name: Salmo gairdneri
    Life Stage: Egg
    Toxicity: (+/-) 0.03 mg/l
    Test: NOEC, hatchability, survival

Soil Organic Carbon/Water Partition Coefficients

  • Koc: 1400 ak
    Formulation: "for Fullerton soil, 0.06% organic carbon"
  • Koc: 5900 ak
    Formulation: "for Apison soil, 0.11% organic carbon"
  • Koc: 5800 ak
    Formulation: for Dormont soil 1.2% organic carbon
  • Koc: Log Koc: 4.15 ay

Octanol-Water Partition Coefficients

  • Log Kow: 4.45 - 4.57 aj
  • Log Kow: Kow: 28200 ao
  • Log Kow: 4.46 ay
  • Log Kow: 4.46 an

Work Cited

d ChemFinder. Cambridge MA: CambridgeSoft Corporation. Retrieved November, 2003 from http://chemfinder.cambridgesoft.com
f Howard, P. H., R. S. Boethling, W. F. Jarvis, W. M. Meylan, and E. M. Michalenko. 1991. Handbook of Environmental Degradation Rates. Lewis Publishers., Chelsea, MI.
aj RAIS. 2005. Risk Assessment Information System. Pages retrieved April, 2005 from http://risk.lsd.ornl.gov/tox/rap_toxp.shtml. U.S. Department of Energy, Office of Environmental Management, Oak Ridge Operations (ORO) Office, Bechtel Jacobs Company LLC, Oak Ridge, TN.
ak Verschueren, K. 2001. Handbook of Environmental Data on Organic Chemicals, 4th edition. John Wiley & Sons, Inc., New York.
an USEPA. 1979. Water-related environmental fate of 129 priority pollutants. Vol. II. Halogenated liphatic hydrocarbons, halogenated ethers, monocyclic aromatics, phthalate esters, polycyclic aromatic hydrocarbons, nitrosamines, and miscellaneous compounds. Environmental Protection Agency, Office of Water Planning and Standards, EPA-440/4-79-029b. NTIS no. PB 80-204381, Washington, DC.
ao Santodonato, J., P. Howard, D. Basu, S.D. Lee, Si Duk, and L. Grant. 1981. Health and ecological assessment of polynuclear aromatic hydrocarbons. Pages 1-364 in Journal of environmental pathology and toxicology, volume 5(1). Park Forest South, Ill. : Pathotox Publishers.
ay Nagpal, N. K. 1993. Ambient Water Quality Criteria For Polycyclic Aromatic Hydrocarbons (PAHs). Pages retrieved April 2005 from http://www.env.gov.bc.ca/wat/wq/BCguidelines/pahs/index.html. British Columbia Ministry of Environment.