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Fenthion

CAS Number: 55-38-9

Basic Information

The chemical structure of Fenthion Synonym(s): Tiguvon; O,O-dimethyl O-(4-methylmercapto-3-methylphenyl) thionophosphate; O,O-dimethyl O-4-(methylmercapto)-3-methylphenyl phosphorothioate; O,O-dimethyl O-(4-methylthio-3-methylphenyl) thiophosphate; O,O-dimethyl-O-[4-(methylthio)-m-tolyl] phosphorothioate; m-cresol, 4-(methylthio)-, O-ester with O,O-dimethyl phosphorothioate; 4-Methylmercapto-3-methylphenyl dimethyl thiophosphate; b 29493; bay 29493; Baycid; bayer 29493; bayer 9007; bayer s-1752; Baytex; Dimethyl O-(3-methyl-4-(methylthio)phenyl) thiophosphate; Dimethyl O-((4-methylmercapto)-3-methylphenyl)thionophosphate; Dimethyl O-(4-(methylthio)-m-tolyl) phosphorothioate; Dimethyl (3-methyl-4-(methylthio)phenyl) phosphorothionate; Dimethyl methylthiotolyl phosphorothioate; BX-1; BX-2; DMTP; Entex; Fenthion; Lebaycid;
Formula: C10H15O3PS2
Molecular Weight: 278.32
Boiling Point (°C): 87 at 0.01 mm Hg
Melting Point (°C): 7.5
Contaminant Type: Fenthion is an insecticide.
Notes: Liquid, slight odor of garlic, insecticide, acaricide

Solubility (in water)

  • Solubility: 55 ppm e
    Temperature (°C): room
  • Solubility: 2 mg/l h
    Temperature (°C): 20
  • Solubility: 6.4 mg/l k
    Temperature (°C): 10
  • Solubility: 9.3 mg/l k
    Temperature (°C): 20
  • Solubility: 11.3 mg/l k
    Temperature (°C): 30

Half-Life (in soil unless otherwise noted)

  • t1/2: 34 days h

Toxicity Effects

  • Organism Type: Birds h
    Common Name: Ducks
    Toxicity: 26 mg/kg
    Test: LD50
  • Organism Type: Birds h
    Common Name: bobwhite quail
    Scientific Name: Colinus virginianus
    Toxicity: <4 mg/kg
    Test: LD50
  • Organism Type: Crustaceans e
    Scientific Name: Caecidotea brevicauda
    Toxicity: 1800 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia pulex
    Toxicity: 0.8 µg/l
    Test: 48h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus fasciatus
    Toxicity: 110 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus lacustris
    Toxicity: 8.4 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus pulex
    Toxicity: 0.014 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans e
    Common Name: Swamp lymnaea
    Scientific Name: Lymnaea stagnalis
    Toxicity: 6.4 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Orconectes nais
    Toxicity: 50 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Common Name: Migrant prawn, oriental shrimp
    Scientific Name: Palaemon macrodactylus
    Toxicity: 30; 5.3 µg/l
    Test: 96h LC50
  • Organism Type: Crustaceans e
    Common Name: Mississippi grass shrimp
    Scientific Name: Palaemonetes kadiakensis
    Toxicity: 5 µg/l
    Test: 120h LC50
  • Organism Type: Crustaceans e
    Common Name: Mississippi grass shrimp
    Scientific Name: Palaemonetes kadiakensis
    Toxicity: 1.5 µg/l
    Test: 20d LC50
  • Organism Type: Crustaceans e
    Scientific Name: Simocephalus serrulatus
    Toxicity: 0.62 µg/l
    Test: 48h LC50
  • Organism Type: Fish e
    Common Name: Sunfish
    Toxicity: 1900 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Perch
    Toxicity: 1700 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Goldfish
    Scientific Name: Carassius auratus
    Toxicity: 3.4 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Goldfish
    Scientific Name: Carassius auratus
    Toxicity: 3400 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Bullhead
    Scientific Name: Cottus gobio
    Toxicity: 1600 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 1.16 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 1200 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Bass
    Scientific Name: Dicentrarchus labrax
    Toxicity: 1500 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Black bullhead
    Scientific Name: Ictalurus melas
    Toxicity: 1620 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Channel catfish
    Scientific Name: Ictalurus punctatus
    Toxicity: 1680 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 1.38 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 1400 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Largemouth bass
    Scientific Name: Micropterus salmoides
    Toxicity: 1540 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Largemouth bass
    Scientific Name: Micropterus salmoides
    Toxicity: 1.54 mg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Coho salmon or silver salmon
    Scientific Name: Oncorhynchus kisutch
    Toxicity: 1.32 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Coho salmon or silver salmon
    Scientific Name: Oncorhynchus kisutch
    Toxicity: 1300 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 9.3 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 900 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Yellow perch
    Scientific Name: Perca flavescens
    Toxicity: 1.65 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Yellow perch
    Scientific Name: Perca flavescens
    Toxicity: 1650 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Minnow
    Scientific Name: Phoxinus phoxinus
    Toxicity: 2400 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 2440 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 2.4 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Columbia River redband trout
    Scientific Name: Salmo gairdneri
    Toxicity: 930 µg/l
    Test: 96h LC50
  • Organism Type: Fish h
    Common Name: Brown trout
    Scientific Name: Salmo trutta
    Toxicity: 1.33 mg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Brown trout
    Scientific Name: Salmo trutta
    Toxicity: 1300 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Brown trout
    Scientific Name: Salmo trutta
    Toxicity: 1330 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Catfish
    Scientific Name: Siluriformes (Order)
    Toxicity: 1700 µg/l
    Test: 96h LC50
  • Organism Type: Mammals h
    Common Name: Rabbits
    Scientific Name: Lagomorpha (order)
    Toxicity: 150 mg/kg
    Test: LD50
  • Organism Type: Mammals k
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Toxicity: 180 mg/kg
    Test: LD50
  • Organism Type: Mammals k
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Gender: Female
    Toxicity: 290 mg/kg
    Test: LD50
  • Organism Type: Mammals k
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Gender: Male
    Toxicity: 375 mg/kg
    Test: LD50
  • Organism Type: Mammals h
    Common Name: Mouse
    Scientific Name: Muridae (Family)
    Toxicity: 88-145 mg/kg
    Test: LD50

Soil Organic Carbon/Water Partition Coefficients

  • Koc: 1684 ml/g k
    Formulation: Sand
    pH Value: 6.9
  • Koc: 948 ml/g k
    Formulation: Sandy loam
    pH Value: 7.7
  • Koc: 2184 ml/g k
    Formulation: Sandy loam
    pH Value: 5.5
  • Koc: 1623 ml/g k
    Formulation: Silty loam
    pH Value: 6.7
  • Koc: 1069 ml/g k
    Formulation: Silty loam
    pH Value: 6.3
  • Koc: 0.89-1.58 k
    Formulation: log

Octanol-Water Partition Coefficients

  • Log Kow: 4.091 h
    Notes: Source did not specify type of partition coeffecient or if value was the log
  • Log Kow: 4.09 k

Work Cited

e Verschueren, K. 1996. Handbook of Environmental Data on Organic Chemicals, 3rd edition. John Wiley & Sons, Inc., New York.
h Extension Toxicology Network. Pages retrieved November, 2003 from http://ace.orst.edu/info/extoxnet/. Oregon State University, Corvallis, OR.
k Montgomery, J. H. 1993. Agrochemicals Desk Reference: Environmental Data. Lewis Publishers, Boca Raton, FL.