Ecological Assessment of Storm Impacts

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Data Collection

Phosmet

CAS Number: 732-11-6

Basic Information

The chemical structure of Phosmet Synonym(s): Appa; Dimethyl phosphorodithioate S-ester with N-(mercaptomethyl)phthalimide; Dimethylphthalimidiomethyl dithiophosphate; Dimethyl S-(phthalimidomethyl) phosphorodithioate; Decemthion; Decemthion P-6; Ftalophos; Imidan; Kemolate; Percolate; Phosmet; Phosm
Formula: C11H12NO4PS2
Molecular Weight: 317.33
Melting Point (°C): 72.5
Contaminant Type: Phosmet is an insecticide.
Notes: Off-white crystalline solid

Solubility (in water)

  • Solubility: 25 mg/l e
    Temperature (°C): 25
  • Solubility: 22-25 mg/l k
    Temperature (°C): 25

Half-Life (in soil unless otherwise noted)

  • t1/2: 4-20 days h

Toxicity Effects

  • Organism Type: Birds h
    Common Name: Red-wing blackbirds
    Scientific Name: Agelaius phoeniceus
    Toxicity: 18 mg/kg
    Test: LD50
  • Organism Type: Birds h
    Common Name: Mallard
    Scientific Name: Anas platyrhynchos
    Toxicity: 1830 mg/kg
    Test: LD50
  • Organism Type: Birds h
    Common Name: pheasant
    Scientific Name: Phasianidae (Family)
    Toxicity: 237 mg/kg
    Test: LD50
  • Organism Type: Birds h
    Common Name: European starlings
    Scientific Name: Sturnus vulgaris
    Toxicity: >100 mg/kg
    Test: LD50
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 2.7 mg/l
    Test: 24h LC50
  • Organism Type: Crustaceans e
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 0.84 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans e
    Scientific Name: Gammarus pseudolimnaeus
    Toxicity: 2.4 µg/l
    Test: 48h LC50
  • Organism Type: Fish k
    Common Name: Channel catfish
    Scientific Name: Ictalurus punctatus
    Toxicity: 11000 µg/l
    Test: 96h LC50
  • Organism Type: Fish k
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 70 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Bluegill
    Scientific Name: Lepomis macrochirus
    Toxicity: 70 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Smallmouth bass
    Scientific Name: Micropterus dolomieu
    Toxicity: 150 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish k
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 560 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 560 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Life Stage: Fingerlings
    Toxicity: >10000 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Life Stage: Fry
    Toxicity: >10000 µg/l
    Test: 96h LC50,S
    Notes: Yolk sac fry
  • Organism Type: Fish e
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Life Stage: Egg
    Toxicity: 7300 µg/l
    Test: 96h LC50,S
    Notes: Eyed eggs
  • Organism Type: Fish e
    Common Name: Chinook salmon or king salmon
    Scientific Name: Oncorhynchus tshawytscha
    Toxicity: 150 µg/l
    Test: 96h LC50,S
  • Organism Type: Fish k
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 7300 µg/l
    Test: 96h LC50
  • Organism Type: Fish e
    Common Name: Fathead minnow
    Scientific Name: Pimephales promelas
    Toxicity: 11000 µg/l
    Test: 96h LC50,S
  • Organism Type: Mammals e
    Common Name: Mouse
    Scientific Name: Muridae (Family)
    Toxicity: 160 mg/kg bw
    Test: LD50
  • Organism Type: Mammals h
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Toxicity: 113-160 mg/kg
    Test: LD50
  • Organism Type: Mammals e
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Toxicity: 26 mg/kg bw
    Test: LD50

Soil Organic Carbon/Water Partition Coefficients

  • Koc: 2.87-2.90 k
    Formulation: log - calculated

Octanol-Water Partition Coefficients

  • Log Kow: 2.83 e
  • Log Kow: 3.0414 h
    Notes: Source did not specify type of partition coeffecient or if value was the log
  • Log Kow: 2.78-3.04 k

Work Cited

e Verschueren, K. 1996. Handbook of Environmental Data on Organic Chemicals, 3rd edition. John Wiley & Sons, Inc., New York.
h Extension Toxicology Network. Pages retrieved November, 2003 from http://ace.orst.edu/info/extoxnet/. Oregon State University, Corvallis, OR.
k Montgomery, J. H. 1993. Agrochemicals Desk Reference: Environmental Data. Lewis Publishers, Boca Raton, FL.