Ecological Assessment of Storm Impacts

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Data Collection

Imidacloprid

CAS Number: 138261-41-3

Basic Information

The chemical structure of Imidacloprid Synonym(s): 1-((6-Chloro-3-pyridinyl)methyl)-N-nitro-imidazolidinimine; ((6-Chloro-3-pyridinyl)methyl)-N-nitro-2-imidazolidinimine; Imidacloprid
Formula: C9H10ClN5O2
Molecular Weight: 255.663
Contaminant Type: Imidacloprid is an insecticide.
Additional Information: Imidacloprid is moderately soluble and has moderate binding affinity to organic materials in soils. However, there is a potential for the compound to move through sensitive soil types including porous, gravelly, or cobbly soils, depending on irrigation practices. h

Solubility (in water)

  • Solubility: 9 - 10 % c
    Formulation: Merit 75 WP
  • Solubility: 0.51 g/l h
    Temperature (°C): 20
  • Solubility: 514 mg/l w
    Temperature (°C): 20
    pH Value: 7

Half-Life (in soil unless otherwise noted)

  • t1/2: 38.9 days w
    Environment: Soil photolysis
  • t1/2: 27-229 days w
    Environment: Depending upon soil type
  • t1/2: 48 days w
    Environment: under vegetation
  • t1/2: 190 days w
    Environment: Without vegetation
  • t1/2: 229 days w
    Environment: without light in field studies
  • t1/2: 997 days w
    Environment: Without light in lab studies
  • t1/2: 40 days w
    Environment: When no organic fertilizers were used
  • t1/2: 124 days w
    Environment: When cow manure was used

Toxicity Effects

  • Organism Type: Crustaceans w
    Common Name: Daphnia
    Scientific Name: Daphnia magna
    Toxicity: 85 mg/l
    Test: 48h LC50
  • Organism Type: Crustaceans w
    Common Name: Mysid shrimp
    Scientific Name: Mysidopsis bahia
    Toxicity: 34 µg/l
    Test: 96h LC50
  • Organism Type: Fish m
    Common Name: Golden orfe
    Toxicity: 237 mg/l
    Test: 96h LC50
  • Organism Type: Fish m
    Common Name: Carp
    Scientific Name: Cyprinus carpio
    Toxicity: 280 mg/l
    Test: 96h LC50
  • Organism Type: Fish w
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: 211 mg/l
    Test: 96h LC50
  • Organism Type: Fish w
    Common Name: Rainbow trout
    Scientific Name: Oncorhynchus mykiss
    Toxicity: >83 mg/l
    Test: 96h LC50
  • Organism Type: Mammals c
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Gender: Female
    Toxicity: 1858 mg/kg
    Test: LD50
    Formulation: Merit 75 WP
  • Organism Type: Mammals c
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Gender: Male
    Toxicity: 2591 mg/kg
    Test: LD50
    Formulation: Merit 75 WP
  • Organism Type: Mammals w
    Common Name: Rat
    Scientific Name: Muridae (Family)
    Toxicity: 450 mg/kg
    Test: LD50

Soil Organic Carbon/Water Partition Coefficients

  • Koc: 132 - 310 w

Octanol-Water Partition Coefficients

  • Log Kow: 0.57 p
  • Log Kow: 0.57 h
    Formulation: At 22 degrees Celcius

Resource Map: Click below to open in a new window to view or print.
Potential applications of this contaminant in the St. Johns Water River Management District

Work Cited

c C&P Press. 2002. EPR Professional Annual CD. Crop Protection Reference. Chemical and Pharmacuetical Press, Inc., New York, NY.
h Extension Toxicology Network. Pages retrieved November, 2003 from http://ace.orst.edu/info/extoxnet/. Oregon State University, Corvallis, OR.
m The University of Manchester Compound Database. Pages retrieved November 2003 from http://www.man.ac.uk/umec/extra/list.html. The University of Manchester, Manchester, England.
p Syracuse Research Corporation Databases. Pages retrieved November, 2003 from: http://esc.syrres.com. Syracuse Research Corporation, North Syracuse, NY.
w Bacey, J. Environmental fate of imidacloprid. Environemntal Monitirung & Pest Management Branch, Department of Pesticide Regulation, Sacramento, CA:1-8.